Symbol | Zr |
Atomic number | 40 |
Group | 4 (Titanium group) |
Period | 5 |
Block | d |
Classification | Transition Metal |
Appearance | Silvery white |
Color | Silver |
Number of protons | 40 p+ |
Number of neutrons | 51 n0 |
Number of electrons | 40 e- |
Phase at STP | Solid |
Density | 6.52 g/cm3 |
Atomic weight | 91.2242 u |
Melting point | 2128 K 1854.85 °C 3370.73 °F |
Boiling point | 4650 K 4376.85 °C 7910.33 °F |
Heat of vaporization | 590.5 kJ/mol |
Electronegativity (Pauling Scale) | 1.33 |
Electron affinity | 41.806 kJ/mol |
Oxidation states | −2, 0, +1, +2, +3, +4 (an amphoteric oxide) |
Ionization energies |
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Discovery | Martin Heinrich Klaproth (1789) |
First isolation | Jöns Jakob Berzelius (1824) |
Discovery of zirconium The zirconium-containing mineral zircon and related minerals (jargoon, hyacinth, jacinth, ligure) were mentioned in biblical writings. The mineral was not known to contain a new element until 1789, when Klaproth analyzed a jargoon from the island of Ceylon (now Sri Lanka). He named the new element Zirkonerde (zirconia). Humphry Davy attempted to isolate this new element in 1808 through electrolysis, but failed. Zirconium metal was first obtained in an impure form in 1824 by Berzelius by heating a mixture of potassium and potassium zirconium fluoride in an iron tube.The crystal bar process (also known as the Iodide Process), discovered by Anton Eduard van Arkel and Jan Hendrik de Boer in 1925, was the first industrial process for the commercial production of metallic zirconium. |